Gatan | AMETEKSkip to Main Content
No options found

X-ray peak intensities

Leverage this quick-reference table for exploring x-ray peak intensities across element series (K, L, M, N) to interpret spectra more accurately, distinguish elemental signals with greater clarity, and make more informed analytical decisions.

 

表示中 1 10 96 結果
Atomic number
Element
Series
K Peak Intensities
L Peak Intensities
M Peak Intensities
N Peak Intensities
3
Lithium
K
Kα = 0.052
4
Beryllium
K
Kα = 0.109
5
Boron
K
Kα = 0.183
6
Carbon
K
Kα = 0.277
7
Nitrogen
K
Kα = 0.392
8
Oxygen
K
Kα = 0.525
9
Fluorine
K
Kα = 0.677
10
Neon
K
Kα = 0.848; Kβ = 0.857
11
Sodium
K
Kα = 1.041; Kβ = 1.067
12
Magnesium
K
Kα = 1.253; Kβ = 1.295

Understanding K, L, M, and N series in EDS

In energy dispersive spectroscopy (EDS/EDX), the K, L, M, and N series reveal how characteristic x-rays are generated during electron transitions within an atom. 


Each series corresponds to the electron shell where the initial vacancy is created, providing a systematic way to interpret emission lines and identify elements.

Electron shell series

  • K series (n = 1): Indicates a vacancy in the innermost shell. These transitions require the highest energy and are most commonly used to analyze light to mid-weight elements.
  • L series (n = 2): Represents a vacancy in the second shell. These lines are typically used for mid- to heavy elements, where K-line excitation may be less accessible.
  • M series (n = 3): Indicates a vacancy in the third shell. These transitions are relevant for high–atomic number elements.
  • N series (n = 4): Corresponds to vacancies in the fourth shell and is used when analyzing the heaviest elements in the periodic table.

Greek letter sub-classifications

Each series is further divided using Greek letters (e.g., Kα, Kβ, Lα), which define the specific transition pathway and relative intensity of the emitted x-rays. Below is information outlining the sub-classifications.

  • Kα = The combined Kα1, Kα2 is used for Z less than 40. The Kα1 only is used for the higher Z values.
  • N = The data set for the N-series peaks is not completely characterized by standardized methods.
K-series relative peak intensities
 

18 ≤ Z < 59

100%

10 – 20 

At Z less than 18, the Kβ decreases in height, and becomes closer to, and is eventually not resolved from the Kα. At Z greater than 59, the Kβ increases in size and sub-peaks can be seen.

L-series relative peak intensities
 21 ≤ Z ≤ 3435 < Z
Ll200 – 6%3.5 – 6%
Ln70 – 3%2 – 3%
1100%100%
120 – 34%35 – 52%
20%0 – 20%
10%0 – 8%
20%0 – 2%

At Z less than 21, the Lα1 and Lβ1 are 0 and Ll is the dominant peak. The Ll is not observable at a Z of 14 or less.

M-series relative peak intensities
 57 ≤ Z ≤ 7070 < Z
Mz140 – 13%6 – 4.5%
100%100%
0 – 45%45 – 57%
20 – 3%3.5 – 1%
M2N40 – 2%0 – 2%


At Z less than 57, the Mα becomes 0% and the Mz is the dominant peak. The Mγ becomes 0 at Z < 50.